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Record W2920259190 · doi:10.1007/s00706-019-2380-6

Determination of viloxazine by differential pulse voltammetry with boron-doped diamond electrode

2019· article· en· W2920259190 on OpenAlexaboutno aff
Maria Madej, Jolanta Kochana, Bogusław Baś

Bibliographic record

VenueMonatshefte für Chemie - Chemical Monthly · 2019
Typearticle
Languageen
FieldEngineering
TopicElectrochemical sensors and biosensors
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryDifferential pulse voltammetryDetection limitSupporting electrolyteCalibration curveAnalytical Chemistry (journal)DiamondElectrochemistryElectrodeTap waterBoronVoltammetryCyclic voltammetryChromatographyPhysical chemistry

Abstract

fetched live from OpenAlex

In recent years, a significant increase in the consumption of various pharmaceuticals, including antidepressants, can be noticed. Depression is classified as chronic or recurrent mood disorder that affects about 121 million people all around the world [ 1 ]. The continuous increase in the consumption of antidepressants has been recorded in most of the well-developed countries. The Eurobarometer report from 2010 indicates that almost 7.5% of the European population use antidepressants regularly [ 2 ]. Such a large intake of antidepressants is also associated with increasing concentration of these drugs and their metabolites in the environment. Many of them are not effectively removed by wastewater treatment, thus they are getting into sources of drinking water, groundwater or bottom sediments [ 3 , 4 , 5 , 6 , 7 ]. World Health Organization in report from 2012 suggests that concentration of pharmaceuticals in environmental waters usually did not exceed 0.1 µg dm −3 [ 8 ]. However, numerous research conducted in different countries such as USA, Canada, China, or Denmark indicate the occurrence of much higher concentrations of antidepressants in surface waters, reaching even 10 µg dm −3 , what is equivalent to approximately 50 nmol dm −3 [ 5 , 9 , 10 , 11 , 12 ]. These observations prove that monitoring the presence of pharmaceutical contaminants in the environmental waters is extremely important. Thus, it is essential to develop analytical methods that allow the determination of antidepressants in both biological and environmental samples with high precision and accuracy.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.002
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0010.001
Open science0.0020.001
Research integrity0.0020.001
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.185
Teacher spread0.182 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations20
Published2019
Admission routes1
Has abstractyes

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Same venueMonatshefte für Chemie - Chemical MonthlySame topicElectrochemical sensors and biosensorsFrench-language works237,207