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Record W2922703860 · doi:10.2118/193543-ms

Development of a Barium Sulphate Scale Inhibitor for Chalk Solid Loaded Conditions

2019· article· en· W2922703860 on OpenAlexaff
Erin Temple, M. M. Jordan, Helen Williams, Sigrid Kjelstrup, Marija Kilibarda, Kolbjorn Johansen

Bibliographic record

VenueSPE International Conference on Oilfield Chemistry · 2019
Typearticle
Languageen
FieldMaterials Science
TopicCalcium Carbonate Crystallization and Inhibition
Canadian institutionsNalco (Canada)
FundersAker BP
KeywordsNucleationBarium sulphateSuspended solidsScalingSeawaterCrystal (programming language)TurbulenceChemistryBariumCrystal growthChemical engineeringMaterials scienceEnvironmental scienceEnvironmental engineeringInorganic chemistryThermodynamicsMathematicsGeologyCrystallographyOrganic chemistryComputer scienceEngineeringPhysicsWastewater

Abstract

fetched live from OpenAlex

Abstract The impact of suspended solids and dynamic conditions on sulphate scale control is well-known. Previous work examined the effect of suspended solids, along with static and turbulent conditions, on one scale inhibitor (Vs-Co). This study has focused on the challenges experienced by an operator of a chalk reservoir field, with a significant amount of carbonate solids in the system, and a high sulphate scale risk due to high barium concentration, injection seawater breakthrough, and cool topside process conditions (20°C). The initial laboratory evaluation showed that the minimum inhibitor concentration (MIC) observed increased from 50ppm to 250ppm after 24 hours (>80% efficiency) under these conditions. A further study investigated whether a reduction in MIC could be achieved with different chemistry. Various chemicals were screened in conventional static jar tests and in stirred tests to induce turbulence incorporating mixed solids. The results showed that many of the conventional scale inhibitor chemistries, working by nucleation inhibition and crystal growth retardation, could not cope with the severe scaling conditions and were less efficient than the incumbent. However, a "novel" scale inhibitor formulation was shown to work more effectively and resulted in a significantly lower MIC than the incumbent. Under sulphate scaling conditions (80:20 FW:SW), VS-Co recorded an MIC of 250ppm which was reduced to ≤100ppm with the novel chemical. This resulted in the opportunity for the operator to reduce their chemical dose rate and logistical costs. This novel chemical works by a combination of nucleation inhibition and crystal growth retardation. As a result of this inhibition mechanism, other operators experiencing similar harsh sulphate scaling conditions could achieve a lower treat rate in high suspended solid loaded systems.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.073
Threshold uncertainty score0.990

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0110.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.029
GPT teacher head0.294
Teacher spread0.265 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2019
Admission routes1
Has abstractyes

Explore more

Same venueSPE International Conference on Oilfield ChemistrySame topicCalcium Carbonate Crystallization and InhibitionFrench-language works237,207