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Record W2929567624 · doi:10.1117/12.2514037

Improving the electrical conductivity of multi-phase polymer composites via plasticizer assisted nanoparticle dispersion

2019· article· en· W2929567624 on OpenAlexaff
Yu‐Chen Sun, Morris Huang, Hani E. Naguib

Bibliographic record

Venuenot available
Typearticle
Languageen
FieldMaterials Science
TopicConducting polymers and applications
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsMaterials scienceComposite materialPercolation thresholdPolymerPlasticizerDispersion (optics)Carbon nanotubePolylactic acidEthylene glycolPercolation (cognitive psychology)ConductivityComposite numberNanoparticlePhase (matter)Thermoplastic polyurethaneCastingNanocompositeChemical engineeringElectrical resistivity and conductivityElastomerNanotechnologyOrganic chemistry

Abstract

fetched live from OpenAlex

It is well-known that electrically conductive polymer composites can be fabricated via incorporating highly conductive fillers such as carbon fibres (CFs) and carbon nanotubes (CNTs) into a polymer system through either melt blending or solvent casting method. Nevertheless, one of the greatest challenges lies in the proper particle dispersion to achieve a low percolation threshold and high conductivity performance. Recently, it was found that CNTs have phasesensitive localization property when incorporated in a composite system formed by two immersible phases, such as polylactic acid (PLA) and thermoplastic polyurethane (TPU). As a result, composites with ultra-low percolation threshold can be formed by tuning the ratio of the two polymer phases. In this study, we reported that such property can be further enhanced via the introduction of a small amount of plasticizer into the polymer system. It was observed that the incorporation of poly(ethylene glycol) (PEG) affected the immiscibility of the two polymer matrix as significant changes in morphologies and thermal behaviours were also detected. Finally, by adding 5 wt% PEG, the electrical conductivity for sample contacting 2.5 wt% CNT increased from to 6.8x10-6 to 3.6x10-4 S/cm. Such results suggest that plasticizer is an effective agent for improving particle distribution and conductivity enhancement.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.282
Teacher spread0.258 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2019
Admission routes1
Has abstractyes

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