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Record W2935826331 · doi:10.1139/cjce-2018-0705

Effect of salts and pH on the removal of perfluorooctanoic acid (PFOA) from aqueous solutions through precipitation and electroflocculation

2019· article· en· W2935826331 on OpenAlexaffvenue
Erica Pensini, Andrea DiNardo, Kristine Lamont, James G. Longstaffe, Abdallah Elsayed, Ashutosh Singh

Bibliographic record

VenueCanadian Journal of Civil Engineering · 2019
Typearticle
Languageen
FieldEnvironmental Science
TopicPer- and polyfluoroalkyl substances research
Canadian institutionsUniversity of Guelph
Fundersnot available
KeywordsPerfluorooctanoic acidPrecipitationAqueous solutionChemistryEnvironmental chemistryInorganic chemistryOrganic chemistryMeteorology

Abstract

fetched live from OpenAlex

This study shows that salt type and pH affect the removal of perfluorooctanoic acid (PFOA) from water through flocculation and electro-enhanced flocculation. PFOA concentrations decreased by approximately 80% with 20 mM FeCl 3 and initial pH = 3–10. Electro-enhanced flocculation at pH = 3 reduced PFOA concentrations in water by approximately 70% with CaCl 2 and KCl, and by 50% with NaCl. At alkaline pH, PFOA removal was approximately 20% with CaCl 2 and KCl. PFOA removal was negligible without salts or with AlCl 3 , and with NaCl at alkaline pH. Differences in PFOA removal are likely due to the settling behaviour of the cation-PFOA complexes formed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.205
Teacher spread0.198 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2019
Admission routes2
Has abstractyes

Explore more

Same venueCanadian Journal of Civil EngineeringSame topicPer- and polyfluoroalkyl substances researchFrench-language works237,207