Structure–property correlations in phase-pure B-doped Q-carbon high-temperature superconductor with a record <i>T</i><sub>c</sub> = 55 K
Bibliographic record
Abstract
Here, we report the detailed structure-property correlations in phase-pure B-doped Q-carbon high-temperature superconductor having a superconducting transition temperature (Tc) of 55 K. This superconducting phase is a result of nanosecond laser melting and subsequent quenching of a highly super undercooled state of molten B-doped C. The temperature-dependent resistivity in different magnetic fields and magnetic susceptibility measurements indicate a type-II Bardeen-Cooper-Schrieffer superconductivity in B-doped Q-carbon thin films. The magnetic measurements indicate that the upper and lower critical fields follow Hc2(0)[1 - (T/Tc)1.77] and Hc1(0)[1 - (T/Tc)1.19] temperature dependence, respectively. The structure-property characterization of B-doped Q-carbon indicates a high density of electronic states near the Fermi-level and large electron-phonon coupling. These factors are responsible for s-wave bulk type superconductivity with enhanced Tc in B-doped Q-carbon. The time-dependent magnetic moment measurements indicate that B-doped Q-carbon thin films follow the Anderson-Kim logarithmic decay model having high values of pinning potential at low temperatures. The crossover from the two-dimensional to the three-dimensional nature of Cooper pair transport at T/Tc = 1.02 also indicates a high value of electron-phonon coupling which is also calculated using the McMillan formula. The superconducting region in B-doped Q-carbon is enclosed by Tc = 55.0 K, Jc = 5.0 × 108 A cm-2, and Hc2 = 9.75 T superconducting parameters. The high values of critical current density and pinning potential also indicate that B-doped Q-carbon can be used for persistent mode of operation in MRI and NMR applications. The Cooper pairs which are responsible for the high-temperature superconductivity are formed when B exists in the sp3 sites of C. The electron energy loss spectroscopy and Raman spectroscopy indicate a 75% sp3 bonded C and 70% sp3 bonded B in the superconducting phase of B-doped Q-carbon which has 27 at% B and rest C. The dimensional fluctuation and magnetic relaxation measurements in B-doped Q-carbon indicate its practical applications in frictionless motors and high-speed electronics. This discovery of high-temperature superconductivity in strongly-bonded and light-weight materials using non-equilibrium synthesis will provide the pathway to achieve room-temperature superconductivity.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".