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Record W2938423695 · doi:10.1039/c9cc00410f

Cucurbituril-mediated quantum dot aggregates formed by aqueous self-assembly for sensing applications

2019· article· en· W2938423695 on OpenAlexafffund
William J. Peveler, Hui Jia, Tiffany Jeen, Kelly Rees, Thomas J. Macdonald, Zhicheng Xia, Weng‐I Katherine Chio, Claire J. Carmalt, W. Russ Algar, Tung‐Chun Lee

Bibliographic record

VenueChemical Communications · 2019
Typearticle
Languageen
FieldChemistry
TopicSupramolecular Chemistry and Complexes
Canadian institutionsVancouver Biotech (Canada)University of British Columbia
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of British ColumbiaRamsay Memorial Fellowships Trust, University College LondonKillam TrustsCanada Research ChairsEngineering and Physical Sciences Research CouncilLeverhulme TrustUniversity of GlasgowMichael Smith Health Research BCCanada Foundation for InnovationAlfred P. Sloan Foundation
KeywordsCucurbiturilQuantum dotAqueous solutionFluorescenceSelf-assemblyNanotechnologyEnergy transferMoleculeFörster resonance energy transferSupramolecular chemistryNanoparticleMaterials scienceChemistryChemical physicsPhysical chemistryOrganic chemistryPhysicsOptics

Abstract

fetched live from OpenAlex

Self-assembled nanoparticles have important applications in energy systems, optical devices and sensors, via the formation of aggregates with controlled interparticle spacing. Here we report aqueous self-assembly of rigid macrocycle cucurbit[7]uril (CB[7]) and fluorescent quantum dots (QDs), and demonstrate the potential of the system for efficient energy transfer and sensing of small molecules.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.226
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.257
Teacher spread0.243 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations15
Published2019
Admission routes2
Has abstractyes

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