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Record W2939006645 · doi:10.1029/2019gl082028

An Odd Oxygen Framework for Wintertime Ammonium Nitrate Aerosol Pollution in Urban Areas: NO<sub>x</sub> and VOC Control as Mitigation Strategies

2019· article· en· W2939006645 on OpenAlexaff
Caroline C. Womack, Erin E. McDuffie, P. M. Edwards, Ryan Bares, J. A. de Gouw, Kenneth S. Docherty, W. P. Dubé, D. L. Fibiger, Alessandro Franchin, J. B. Gilman, Lexie Goldberger, Ben H. Lee, John C. Lin, Russell Long, A. M. Middlebrook, Dylan B. Millet, Alexander Moravek, J. G. Murphy, Patricia K. Quinn, Theran P. Riedel, J. M. Roberts, Joel A. Thornton, Patrick R. Veres, Andrew Whitehill, R. J. Wild, C. Warneke, Bin Yuan, Munkhbayar Baasandorj, Steven S. Brown

Bibliographic record

VenueGeophysical Research Letters · 2019
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsYork UniversityUniversity of TorontoDalhousie University
FundersUtah Department of Environmental QualityUtah State UniversityNational Oceanic and Atmospheric AdministrationU.S. Environmental Protection Agency
KeywordsNitrateEnvironmental scienceAerosolPollutionOzoneAmmoniumEnvironmental chemistryPollutantNOxAir pollutionAmmonium nitrateAir quality indexNitrogen oxideAtmospheric sciencesEnvironmental engineeringChemistryMeteorologyGeographyEcologyCombustionGeology

Abstract

fetched live from OpenAlex

Abstract Wintertime ammonium nitrate aerosol pollution is a severe air quality issue affecting both developed and rapidly urbanizing regions from Europe to East Asia. In the United States, it is acute in western basins subject to inversions that confine pollutants near the surface. Measurements and modeling of a wintertime pollution episode in Salt Lake Valley, Utah, demonstrate that ammonium nitrate is closely related to photochemical ozone through a common parameter, total odd oxygen, O x,total . We show that the traditional nitrogen oxide and volatile organic compound (NOx‐VOC) framework for evaluating ozone mitigation strategies also applies to ammonium nitrate. Despite being nitrate‐limited, ammonium nitrate aerosol pollution in Salt Lake Valley is responsive to VOCs control and, counterintuitively, not initially responsive to NO x control. We demonstrate simultaneous nitrate limitation and NO x saturation and suggest this phenomenon may be general. This finding may identify an unrecognized control strategy to address a global public health issue in regions with severe winter aerosol pollution.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.694
Threshold uncertainty score0.677

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.261
Teacher spread0.249 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations142
Published2019
Admission routes1
Has abstractyes

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