Synthesis, Characterization, Thermogravimetric and Antioxidant Studies of New Cu(II), Fe(II), Mn(II), Cu(II), Zn(II), Co(II) and Ni(II) Complexes with Benzoic Acid and 4,4,4-Trifluoro-1-(2-naphthyl)-1,3-butanedione
Bibliographic record
Abstract
Six new Mn(II), Fe(II), Co(II), Ni (II), Cu(II) and Zn(II) complexes with benzoic acid (L) and 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione (L1), of the molecular formulae [MnLL1]·H2O (1), [FeLL1]·H2O (2), [CoLL1] (3), [NiLL1]·H2O (4), [CuLL1] (5) and [ZnLL1] (6), respectively, have been synthesized. The molecular structures of the complexes were determined by spectrophotometric studies using ir, 1H and 13C nmr, es and mass spectrophotometry revealed that the geometries of the complexes 1, 2, 3, and 6 are tetrahedral, while 4 and 5 have square planar geometry. These geometries were supported by their magnetic moments data. The coordination of the ligands to the metal ion are through their oxygen atoms. TGA studies showed that they are thermally stable. Their antioxidant studies revealed that they are good antioxidants.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.001 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".