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Record W2944440098 · doi:10.1038/s41598-019-43500-3

Temperature and oxygen adsorption coupling effects upon the surface tension of liquid metals

2019· article· en· W2944440098 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueScientific Reports · 2019
Typearticle
Languageen
FieldEngineering
TopicMetallurgical Processes and Thermodynamics
Canadian institutionsPolytechnique Montréal
FundersNatural Sciences and Engineering Research Council of CanadaUniversité de MontréalCanadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of CanadaCompute Canada
KeywordsSurface tensionOxygen tensionOxygenAdsorptionAluminiumWork functionMetalChemistryFormalism (music)ImpurityMaximum bubble pressure methodThermodynamicsMaterials scienceMetallurgyPhysical chemistryPhysicsOrganic chemistry

Abstract

fetched live from OpenAlex

An accurate knowledge of the surface tension of liquid metals is critical for many theoretical and practical applications, especially in the current context of emerging growth of nanotechnology. The surface tension and its temperature dependence are drastically influenced by the level of impurities in the metal such as oxygen, sulphur or carbon. For this reason, experimental surface tension data of metals reported in literature are scattered. Strictly speaking, when referring to the surface tension of liquid metals, both variables temperature and oxygen content must be specified. There exists no clear formalism describing the coupling effect temperature and the oxygen content upon the surface tension of liquid metals. The aim of this work is to fill this gap. A thermodynamically self-consistent formulation for the surface tension of liquid metals and semiconductors as a function of temperature and oxygen content is established. According to the proposed formalism, a reliable expression for the surface tension of pure and oxygen saturated metals is then derived. The proposed model is found to be in good agreement with available experimental data, showing a good predictive capability. Aluminium is chosen and thoroughly evaluated as a case study, due to its very high sensitivity to oxygen level. Its surface tension is explicitly formulated as a function of temperature and oxygen content.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.722
Threshold uncertainty score0.263

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.199
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it