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Record W2946666423 · doi:10.1021/acsomega.9b01076

Performances of Alkaloid Extract from<i>Rauvolfia macrophylla</i>Stapf toward Corrosion Inhibition of C38 Steel in Acidic Media

2019· article· en· W2946666423 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueACS Omega · 2019
Typearticle
Languageen
FieldMaterials Science
TopicCorrosion Behavior and Inhibition
Canadian institutionsnot available
FundersAgence Universitaire de la FrancophonieStyrelsen för Internationellt Utvecklingssamarbete
KeywordsCorrosionAdsorptionElectrochemistryAlkaloidCathodic protectionCorrosion inhibitorChemistryMaterials scienceNuclear chemistryMetallurgyElectrodeOrganic chemistry

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide Alkaloid extract from Rauvolfia macrophylla Stapf (AERMS) was studied as the corrosion inhibitor for C38 steel in 1 M HCl and 0.5 M H 2 SO 4 using electrochemistry and surface analysis. The corrosion inhibition was efficient and proceeds via adsorption of AERMS on the steel surface due to the active functional groups present in the molecules. AERMS acts as a mixed inhibitor in HCl and as a cathodic inhibitor in H 2 SO 4 . In H 2 SO 4 corrosive medium, the presence of iodides improves the adsorption of the alkaloid molecules by reducing the surface charge of the electrode and thus substantially decreases the corrosion rate. Two pure alkaloids (tetrahydroalastonine (THA) and perakine (PER)) were quantitatively isolated from AERMS, and their anticorrosive properties for C38 steel in 1 M HCl and 0.5 M H 2 SO 4 were evaluated. THA showed the highest efficiency while the performance of PER was less important compared to the extract. This confirms that the efficiency of AERMS was the result of the complementary action of the chemical compounds present in the extract.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.014
Threshold uncertainty score0.751

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.240
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it