Diphospha‐Ureas from the Phosphaketene Ph<sub>3</sub>GePCO
Bibliographic record
Abstract
Abstract The phosphaketene Ph3GePCO is shown to react with the phosphide KP(tBu)2 to generate the anion [Ph3GePC(O)P(tBu)2]− 1. This species reacts with CH3I or ClGePh3 to give the dissymmetric diphospha‐ureas (tBu)2PC(O)P(GePh3)(CH3) 2 and (Ph3Ge)2PC(O)P(tBu)2 3 respectively. Sequential treatment of 2 with a base and CH3I affords a route to (tBu)2PC(O)P(CH3)2 5. These species are products of the first modular diphospha‐urea synthesis. The subsequent thermal and photochemical reactivity of these species was also probed and described.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".