A novel self-complementary three-dimensional inorganic network organized by H-bond dimers of inorganic chains Synthesis and crystal structure of (C<sub>6</sub>H<sub>16</sub>N<sub>2</sub>)[Zn(HPO<sub>4</sub>)<sub>2</sub>]
Why this work is in the frame
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Bibliographic record
Abstract
A novel organic-templated zincophosphate, namely (C 6 H 16 N 2 )[Zn(HPO 4 ) 2 ], was hydrothermally synthesized and X-ray single-crystal structural analysis reveals that the anions [Zn(HPO 4 ) 2 ] 2 , which have square-twisted chains containing corner-sharing four-rings of alternating ZnO 4 and PO 4 tetrahedra, are assemblied via self-complementary strong and symmetrical hydrogen-bonding R 2 2 (8) synthons between the phosphate groups into three-dimensional hydrogen bond frameworks featuring three-dimensional intersecting pseudochannels. The doubly protonated 2,5-dimethylpiperazinium cations are attached to the three-dimensional inorganic framework via N-H···O hydrogen bonds to strengthen the 3-D network.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.002 | 0.001 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it