A novel self-complementary three-dimensional inorganic network organized by H-bond dimers of inorganic chains Synthesis and crystal structure of (C<sub>6</sub>H<sub>16</sub>N<sub>2</sub>)[Zn(HPO<sub>4</sub>)<sub>2</sub>]
Bibliographic record
Abstract
A novel organic-templated zincophosphate, namely (C6H16N2)[Zn(HPO4)2], was hydrothermally synthesized and X-ray single-crystal structural analysis reveals that the anions [Zn(HPO4)2]2, which have square-twisted chains containing corner-sharing four-rings of alternating ZnO4 and PO4 tetrahedra, are assemblied via self-complementary strong and symmetrical hydrogen-bonding R22(8) synthons between the phosphate groups into three-dimensional hydrogen bond frameworks featuring three-dimensional intersecting pseudochannels. The doubly protonated 2,5-dimethylpiperazinium cations are attached to the three-dimensional inorganic framework via N-H···O hydrogen bonds to strengthen the 3-D network.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".