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Record W2949603651 · doi:10.1002/chin.201601050

ChemInform Abstract: Nickel‐Catalyzed Decarbonylative Coupling of Aryl Esters and Arylboronic Acids.

2015· article· en· W2949603651 on OpenAlexaffabout
Nicole A. LaBerge, Jennifer A. Love

Bibliographic record

VenueChemInform · 2015
Typearticle
Languageen
FieldChemistry
TopicCatalytic Cross-Coupling Reactions
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsChemistryArylCatalysisNickelCoupling (piping)Combinatorial chemistryDecarbonylationOrganic chemistryMedicinal chemistryMetallurgyAlkyl

Abstract

fetched live from OpenAlex

ChemInformVolume 47, Issue 1 Preparative Organic Chemistry ChemInform Abstract: Nickel-Catalyzed Decarbonylative Coupling of Aryl Esters and Arylboronic Acids. Nicole A. LaBerge, Nicole A. LaBerge Dep. Chem., Univ. British Columbia, Vancouver, B. C. V6T 1Z1, Can.Search for more papers by this authorJennifer A. Love, Jennifer A. Love Dep. Chem., Univ. British Columbia, Vancouver, B. C. V6T 1Z1, Can.Search for more papers by this author Nicole A. LaBerge, Nicole A. LaBerge Dep. Chem., Univ. British Columbia, Vancouver, B. C. V6T 1Z1, Can.Search for more papers by this authorJennifer A. Love, Jennifer A. Love Dep. Chem., Univ. British Columbia, Vancouver, B. C. V6T 1Z1, Can.Search for more papers by this author First published: 14 July 2016 https://doi.org/10.1002/chin.201601050Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume47, Issue1December 17, 2015 RelatedInformation

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.100
Threshold uncertainty score0.334

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0020.002
Science and technology studies0.0010.000
Scholarly communication0.0020.002
Open science0.0020.001
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.1000.073

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.271
Teacher spread0.247 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2015
Admission routes2
Has abstractyes

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