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Record W2950146326 · doi:10.1149/1.2795106

Characterization of LiFePO4 at a Nanoscopic Scale in Relation to the Mode of Preparation

2007· article· en· W2950146326 on OpenAlexaff
A. Mauger, Atmane Ait-Salah, Michel Massot, François Gendron, Karim Zaghib, C. Julien

Bibliographic record

VenueECS Transactions · 2007
Typearticle
Languageen
FieldEngineering
TopicAdvancements in Battery Materials
Canadian institutionsHydro-Québec
Fundersnot available
KeywordsImpurityFourier transform infrared spectroscopyMaterials scienceRaman spectroscopyCharacterization (materials science)Lithium (medication)Analytical Chemistry (journal)Nanoscopic scaleDiffractionElectrochemistryCathodePhase (matter)SpectroscopyFourier transformInfrared spectroscopyChemical engineeringNanotechnologyChemistryOpticsChromatographyPhysical chemistryElectrodePhysics

Abstract

fetched live from OpenAlex

We present a review of the structural properties of LiFePO4. Depending on the mode of preparation, different impurities can poison this material. These impurities are identified and a quantitative estimate of their concentrations is deduced from the combination of X-ray diffraction (XRD) analysis, Fourier transform infrared (FTIR) spectroscopy, Raman scattering (RS) spectroscopy and magnetic measurements. An optimized preparation provides samples with carbon coated particles free of any impurity phase, insuring structural stability and electrochemical performance that justify the use of this material as a cathode element a new generation of lithium secondary batteries.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.352
Threshold uncertainty score0.198

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.255
Teacher spread0.246 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2007
Admission routes1
Has abstractyes

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