Recent Adventures with the Pauson‐Khand Reaction in Total Synthesis
Bibliographic record
Abstract
This chapter contains sections titled: Introduction (+)-Epoxydictymene (±)-Pentalenene and (-)-Pentalenene The Tandem Pauson-Khand Reaction Directed Towards the Synthesis of Dicyclopentapentalenes Enantioselective Total Synthesis of (-)-α-Kainic Acid The Total Synthesis of Paecilomycine A The Total Synthesis of (+)-Achalensolide The Total Synthesis of (-)-Alstonerine The Total Synthesis of (±)-8α-Hydroxystreptazolone The Formal Total Synthesis of (±)-α- and β-Cedrene Additional Applications of the Pauson-Khand Reaction in Total Synthesis Conclusions Acknowledgements References
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.021 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".