MétaCan
Menu
Back to cohort
Record W2951884821 · doi:10.1002/cem.3137

Simulation of <b>1</b>/<i>f</i><sup><i>α</i></sup> noise for analytical measurements

2019· article· en· W2951884821 on OpenAlexaff
Stephen Driscoll, Michael Dowd, Peter D. Wentzell

Bibliographic record

VenueJournal of Chemometrics · 2019
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Chemometric Analyses
Canadian institutionsDalhousie University
Fundersnot available
KeywordsNoise (video)Gradient noiseNoise spectral densityNoise measurementValue noiseNoise powerAlgorithmGaussian noiseImpulse noiseMathematicsNoise reductionComputer sciencePhysicsNoise floorPower (physics)Noise figureAcousticsArtificial intelligence

Abstract

fetched live from OpenAlex

A simple procedure is described that can be used to generate 1/fα noise, also known as power law noise, in simulated analytical measurement vectors. Certain types of power law noise, such as pink noise (α=1), dominate many types of analytical signals, so its simulation is important in optimizing data processing strategies. In this work, simulated 1/fα error sequences are created directly from white noise via the theoretical measurement error covariance matrix (ECM) by rotation and scaling. The 1/fα ECM is obtained from the coefficients of a finite impulse response filter and is easily adapted to generate multiplicative 1/fα noise that is probably more common for analytical systems exhibiting proportional noise characteristics. Simulating 1/fα noise directly from the ECM offers two main advantages. First, 1/fα noise can be easily simulated in the presence of other common analytical measurement errors by additive combination of the ECMs. Second, the theoretical ECM can be used to model real experimental measurement noise. It is shown that the power spectral density function of measurement error sequences generated by the proposed method closely approximates the theoretical behaviour of 1/fα noise. To demonstrate the utility of this method in evaluating data processing methods, simulated data exhibiting 1/f (pink) noise is analyzed by maximum likelihood principal component analysis (MLPCA) that takes measurement error structure into account, and baseline noise is simulated using brown noise to test baseline fitting by asymmetric least squares (AsLS).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.004
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.052
GPT teacher head0.325
Teacher spread0.273 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2019
Admission routes1
Has abstractyes

Explore more

Same venueJournal of ChemometricsSame topicSpectroscopy and Chemometric AnalysesFrench-language works237,207