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Record W2951884821 · doi:10.1002/cem.3137

Simulation of <b>1</b>/<i>f</i><sup><i>α</i></sup> noise for analytical measurements

2019· article· en· W2951884821 on OpenAlex
Stephen Driscoll, Michael Dowd, Peter D. Wentzell

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Chemometrics · 2019
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Chemometric Analyses
Canadian institutionsDalhousie University
Fundersnot available
KeywordsNoise (video)Gradient noiseNoise spectral densityNoise measurementValue noiseNoise powerAlgorithmGaussian noiseImpulse noiseMathematicsNoise reductionComputer sciencePhysicsNoise floorPower (physics)Noise figureAcousticsArtificial intelligence

Abstract

fetched live from OpenAlex

A simple procedure is described that can be used to generate 1/ f α noise, also known as power law noise, in simulated analytical measurement vectors. Certain types of power law noise, such as pink noise ( α =1), dominate many types of analytical signals, so its simulation is important in optimizing data processing strategies. In this work, simulated 1/ f α error sequences are created directly from white noise via the theoretical measurement error covariance matrix (ECM) by rotation and scaling. The 1/ f α ECM is obtained from the coefficients of a finite impulse response filter and is easily adapted to generate multiplicative 1/ f α noise that is probably more common for analytical systems exhibiting proportional noise characteristics. Simulating 1/ f α noise directly from the ECM offers two main advantages. First, 1/ f α noise can be easily simulated in the presence of other common analytical measurement errors by additive combination of the ECMs. Second, the theoretical ECM can be used to model real experimental measurement noise. It is shown that the power spectral density function of measurement error sequences generated by the proposed method closely approximates the theoretical behaviour of 1/ f α noise. To demonstrate the utility of this method in evaluating data processing methods, simulated data exhibiting 1/ f (pink) noise is analyzed by maximum likelihood principal component analysis (MLPCA) that takes measurement error structure into account, and baseline noise is simulated using brown noise to test baseline fitting by asymmetric least squares (AsLS).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.003
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.606
Threshold uncertainty score0.996

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.003
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.003
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.052
GPT teacher head0.325
Teacher spread0.273 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it