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Record W2952243407 · doi:10.1111/iar.12310

Fourier transform infrared microspectroscopic characterization of Neoproterozoic organic microfossils from the Fifteenmile Group in Yukon, Canada

2019· article· en· W2952243407 on OpenAlexaboutno aff
Motoko Igisu, Tsuyoshi Komiya, Stanley M. Awramik, Yuka Ikemoto, Yechuan Geng, Hiroki Uehara, Ken Takai

Bibliographic record

VenueIsland Arc · 2019
Typearticle
Languageen
FieldEnvironmental Science
TopicMethane Hydrates and Related Phenomena
Canadian institutionsnot available
FundersJapan Society for the Promotion of ScienceMinisterul Educaţiei Naţionale
KeywordsFourier transform infrared spectroscopyChemistryCharacterization (materials science)InfraredAffinitiesGeologyMicrometerInfrared spectroscopyMineralogyAnalytical Chemistry (journal)Materials scienceStereochemistryChemical engineeringOrganic chemistryNanotechnology

Abstract

fetched live from OpenAlex

Abstract Conventional and synchrotron radiation‐based (SR) Fourier transform infrared microspectroscopies (micro‐FTIR) were applied to four types of ~ 810 Ma organic‐walled microfossils together with diffuse organic matter (OM) and one irregularly shaped structure from the Fifteenmile Group, in Yukon, Canada, for their chemical characterization. The microfossils comprised one filamentous type and three coccoidal types. Micro‐FTIR mapping analysis revealed the micrometer‐scale, spatial distribution of organic components (aliphatic C‐H bonds) and carbonate in the microfossils. Based on comparisons of CH 3 /CH 2 peak height ratios (R 3/2 ) and morphologies of the microfossils (without the diffuse OM) to those of previously described Proterozoic microfossils, possible affinities of the microfossils are suggested, as follows. Palaeolyngbya ? and Glenobotrydion belong to bacteria. Myxococcoides is not clearly characterized due to the significant mixing with diffuse OM containing abundant aliphatic C‐H groups. The irregularly shaped structure may represent a eukaryote. The diffuse OM may represent a mixture of decomposed microbial cells and extracellular polymeric substances (EPS). SR micro‐FTIR measurements of two coccoid types ( Glenobotrydion and Unnamed Coccoid Form D) revealed that the R 3/2 values of the internal spots with wall structures are similar to those without wall structures in Glenobotrydion : those values from Unnamed Coccoid Form D were different. The results suggest that these two coccoids are different chemically as well as morphologically. Micro‐FTIR characterization of the organic‐walled microfossils together with morphological analysis provides new insight into their biological affinities.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.726
Threshold uncertainty score0.996

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0050.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.002
GPT teacher head0.160
Teacher spread0.158 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2019
Admission routes1
Has abstractyes

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