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1,2,3,5‐Dithiadiazolyl Radicals

2019· other· en· W2953242111 on OpenAlexaff
Mitchell A. Nascimento, Jeremy M. Rawson

Bibliographic record

VenueEncyclopedia of Inorganic and Bioinorganic Chemistry · 2019
Typeother
Languageen
FieldMaterials Science
TopicMagnetism in coordination complexes
Canadian institutionsUniversity of Windsor
Fundersnot available
KeywordsRadicalMagnetismBlock (permutation group theory)Ring (chemistry)Solid-stateRange (aeronautics)ChemistryOxidation stateElectronPhotochemistryMaterials scienceChemical physicsPhysical chemistryPhysicsOrganic chemistryMetalCondensed matter physicsNuclear physics

Abstract

fetched live from OpenAlex

Abstract Synthetic routes to dithiadiazolyl radicals are described. The propensity for forming π*–π* dimers in the solid state is discussed and their electron transport properties, photoconducting behavior, magnetism, and emissive response described. The 1,2,3,5‐dithiadiazolyl (DTDA) ring system has a diverse range of oxidation states and the coordination chemistry of d‐ and f‐block metals with DTDA rings ranging from 0 to −3 oxidation states are described.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.246
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0770.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.208
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2019
Admission routes1
Has abstractyes

Explore more

Same venueEncyclopedia of Inorganic and Bioinorganic ChemistrySame topicMagnetism in coordination complexesFrench-language works237,207