Electrospun PEDOT:PSS Electrolytic Capacitors Electrodes for Microelectronic Energy Storage
Bibliographic record
Abstract
This thesis investigates the use of electrospinning process as an additive fabrication method to deposit porous ultrahigh surface area poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PE-DOT:PSS) as electrodes for use in electrolytic capacitors for powering microelectronic circuits.An electrospinning process for depositing high PEDOT content fibres is established using Baytron P/Poly(ethlyene Oxide)/Dimethyl Sulfoxide.The electrospun fibre mats are utilized as both the anode and cathode with Lithium Perchlorate (LiClO4)/ Propylene Carbonate (PC) as the electrolyte.This work investigates the electrochemical operation, charge storage metrics, and lifecycle through cyclic voltammetry, DC charging, and electrochemical impedance spectroscopy.Results demonstrate non-faradaic charge storage dominates up to 1.1 V with a maximum achieved areal capacitance and energy storage of 5.25 mF cm -2 and 3.18 mJ cm -2 respectively.The lifecycle investigation finds a 4 % capacitance increase after 20,000 1.1 V cycles at 0.5 Hz.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.003 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".