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Record W2962492223 · doi:10.1149/2.0601912jes

Laser Surface Roughening of Aluminum Foils for Supercapacitor Current Collectors

2019· article· en· W2962492223 on OpenAlexafffund
Dongfang Yang, Alexis Laforgue

Bibliographic record

VenueJournal of The Electrochemical Society · 2019
Typearticle
Languageen
FieldMaterials Science
TopicSupercapacitor Materials and Fabrication
Canadian institutionsNational Research Council Canada
FundersNatural Resources Canada
KeywordsMaterials scienceCurrent collectorLaser ablationSupercapacitorAluminiumCarbon fibersLayer (electronics)CoatingLaserComposite materialDielectric spectroscopyMicrostructureMetallurgyElectrodeCapacitanceElectrochemistryOpticsChemistryElectrolyte

Abstract

fetched live from OpenAlex

Thin aluminum foils were surface roughened by laser ablation in high vacuum conditions. Their performance as current collectors for carbon-based supercapacitors were evaluated by impedance spectroscopy, cyclic voltammetry and galvanostatic cycling, and compared with those of gold plates, flat aluminum foils and commercially available carbon-coated aluminum foils (Z-flo). The results revealed that the laser surface treatment significantly enhances the electronic contact between the current collector and the active materials layers. The benefits in interface enhancement are comparable to those of a carbon coating. High power performances were reached thanks to a significantly decreased internal resistance. Long-term cycling performance revealed a slight but continuous capacity fading for supercapacitor cells having laser-treated current collectors, which was caused by the progressive growth of a surface aluminum oxide layer on the current collector. Cells assembled with carbon-coated collectors did not display the same fading thanks to the protection provided by the interfacial carbon layer. This work demonstrates that laser ablation in vacuum is a promising technique for the preparation supercapacitor current collectors with surface oxide-free and controllable surface microstructures toward specific active materials.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.244
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations14
Published2019
Admission routes2
Has abstractyes

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Same venueJournal of The Electrochemical SocietySame topicSupercapacitor Materials and FabricationFrench-language works237,207