Crystal structures of an imidazo[1,5-<i>a</i>]pyridinium-based ligand and its (C<sub>13</sub>H<sub>12</sub>N<sub>3</sub>)<sub>2</sub>[CdI<sub>4</sub>] hybrid salt
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Bibliographic record
Abstract
The monocation product of the oxidative condensation–cyclization between two molecules of pyridine-2-carbaldehyde and one molecule of CH 3 NH 2 ·HCl in methanol, 2-methyl-3-(pyridin-2-yl)imidazo[1,5- a ]pyridinium, was isolated in the presence of metal ions as bis[2-methyl-3-(pyridin-2-yl)imidazo[1,5- a ]pyridin-2-ium] tetraiodocadmate, (C 13 H 12 N 3 ) 2 [CdI 4 ], (I), and the mixed chloride/nitrate salt, bis[2-methyl-3-(pyridin-2-yl)imidazo[1,5- a ]pyridin-2-ium] 1.5-chloride 0.5-nitrate trihydrate, 2C 13 H 12 N 3 + ·1.5Cl − ·0.5NO 3 − ·3H 2 O, (II). Hybrid salt (I) crystallizes in the space group P 2 1 / n with two [ L ] 2 [CdI 4 ] molecules in the asymmetric unit related by pseudosymmetry. In the crystal of (I), layers of organic cations and of tetrahalometallate anions are stacked parallel to the ab plane. Antiparallel L + cations disposed in a herring-bone pattern form π-bonded chains through aromatic stacking. In the inorganic layer, adjacent tetrahedral CdI 4 units have no connectivity but demonstrate close packing of iodide anions. In the crystal lattice of (II), the cations are arranged in stacks propagating along the a axis; the one-dimensional hydrogen-bonded polymer built of chloride ions and water molecules runs parallel to a column of stacked cations.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.001 |
| Meta-epidemiology (narrow) | 0.004 | 0.004 |
| Meta-epidemiology (broad) | 0.004 | 0.003 |
| Bibliometrics | 0.004 | 0.006 |
| Science and technology studies | 0.003 | 0.004 |
| Scholarly communication | 0.001 | 0.003 |
| Open science | 0.006 | 0.003 |
| Research integrity | 0.003 | 0.006 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it