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Record W2967880813 · doi:10.3390/s19163508

Real-Time Ozone Sensor Based on Selective Oxidation of Methylene Blue in Mesoporous Silica Films

2019· article· en· W2967880813 on OpenAlex
Christelle Ghazaly, Marc Hébrant, Eddy Langlois, Blandine Castel, Marianne Guillemot, Mathieu Etienne

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

aboutThe title or abstract carries a Canadian signal from the geographic lexicon.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueSensors · 2019
Typearticle
Languageen
FieldEnvironmental Science
TopicAir Quality Monitoring and Forecasting
Canadian institutionsnot available
Fundersnot available
KeywordsOzoneDetection limitRelative humidityMesoporous silicaMaterials scienceLinear rangeMethylene blueMesoporous materialEnvironmental scienceAtmosphere (unit)Response timeAnalytical Chemistry (journal)Environmental chemistryChemistryComputer scienceMeteorologyChromatographyOrganic chemistryCatalysis

Abstract

fetched live from OpenAlex

Sensitive and selective personal exposure monitors are needed to assess ozone (O3) concentrations in the workplace atmosphere in real time for the analysis and prevention of health risks. Here, a cumulative gas sensor using visible spectroscopy for real-time O3 determination is described. The sensing chip is a mesoporous silica thin film deposited on transparent glass and impregnated with methylene blue (MB). The sensor is reproducible, stable for at least 50 days, sensitive to 10 ppb O3 (one-tenth of the occupational exposure limit value in France, Swiss, Canada, U.K., Japan, and the USA) with a measurement range tested up to 500 ppb, and insensitive to NO2 and to large variation in relative humidity. A model and its derivative as a function of time are proposed to convert in real time the sensor response to concentrations, and an excellent correlation was obtained between those data and reference O3 concentrations. This sensor is based on a relatively cheap sensing material and a robust detection system, and its analytical performance makes it suitable for monitoring real-time O3 concentrations in workplaces to promote a safer environment for workers.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.153
Threshold uncertainty score0.780

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.239
Teacher spread0.229 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it