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Record W2970112389 · doi:10.1063/1.5121669

Polymer hollow fiber membranes for gas separation: A comparison between three commercial resins

2019· article· en· W2970112389 on OpenAlexaff
Serge Kaliaguine, Denis Rodrigue

Bibliographic record

VenueAIP conference proceedings · 2019
Typearticle
Languageen
FieldEngineering
TopicMembrane Separation and Gas Transport
Canadian institutionsUniversité LavalCentre National en Électrochimie et en Technologies EnvironnementalesCollège Shawinigan
Fundersnot available
KeywordsPolyetherimideMembraneMaterials sciencePermeanceGas separationPolymerPermeationScanning electron microscopePhase inversionHollow fiber membraneChemical engineeringCastingFiberComposite materialPolymer chemistryChemistry

Abstract

fetched live from OpenAlex

Polymer hollow fibre membranes are becoming more and more used for gas separation. In this work, asymmetric hollow fibre membranes were prepared by a phase inversion technique with three commonly used commercial polymers: polyethersulfone (PES), polyetherimide (Ultem® 1000), and polyimides (Matrimid® 5218). The effect of spinning parameters (composition of the dope and bore solution, bore flow rate, air gap distance, temperature of the spinneret and coagulation bath, as well as take-up speed) on the membrane morphology and gas permeation properties was investigated. The membrane separation performances were characterized in terms of gas transport properties (perméance/selectivity) for different gases (H2, CO2, O2, N2, CH4) to relate this information with their morphology studied by scanning electron microscopy (SEM). Furthermore, dense flat membranes from the same materials were prepared by solvent casting to investigate the relationships between the gas separation performance and membrane configuration (hollow fibers vs. compact flat membrane). Finally, a comparison between the apparent skin layer thickness from O2 permeability/permeance and SEM image gave good agreement.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.038
GPT teacher head0.285
Teacher spread0.248 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations20
Published2019
Admission routes1
Has abstractyes

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Same venueAIP conference proceedingsSame topicMembrane Separation and Gas TransportFrench-language works237,207