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Record W2973055646 · doi:10.1021/acs.analchem.9b01686

Multiscale Visualization of Colloidal Particle Lens Array Mediated Plasma Dynamics for Dielectric Nanoparticle Enhanced Femtosecond Laser-Induced Breakdown Spectroscopy

2019· article· en· W2973055646 on OpenAlex
Mengmeng Wang, Lan Jiang, Sumei Wang, Qitong Guo, Feng Tian, Zhuyuan Chu, Jin Zhang, Xin Li, Yongfeng Lu

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAnalytical Chemistry · 2019
Typearticle
Languageen
FieldEngineering
TopicLaser-induced spectroscopy and plasma
Canadian institutionsUniversity of Waterloo
FundersMinistry of Science and Technology of the People's Republic of ChinaMinistry of Human Resources and Social SecurityNational Natural Science Foundation of China
KeywordsChemistryFemtosecondNanoparticleColloidal particlePlasmaParticle (ecology)DielectricColloidLaser-induced breakdown spectroscopyLaserSpectroscopyDielectric spectroscopyChemical physicsOptoelectronicsNanotechnologyOpticsPhysical chemistryMaterials science

Abstract

fetched live from OpenAlex

A multiscale visualization of silica colloidal particle lens array (CPLA) assisted laser ablation of copper is investigated. The distributed holes on a crater of CPLA-deposited Cu (CPLA-Cu) show a near-field effect by the silica nanoparticles (NPs), and the plasma emission signal of CPLA-Cu is 3-5 times as strong as that of Cu. Time-resolved plasma expansion, shockwave propagation, plasma plume emission, and nanoparticle distribution are observed and analyzed for ablations on both Cu and CPLA-Cu substrates. The initial expansion of plasma generated on CPLA-Cu is faster than that of pristine Cu. The shockwave of CPLA-Cu is rounder and its plasma plume is wider than those of Cu. The nanoparticle distribution shows a strong lateral collision during plume ejection for CPLA-Cu. Plasma characterization shows the increased plasma temperature is the key reason for femtosecond laser-induced breakdown spectroscopy (fs-LIBS) signal enhancement. This work demonstrates the signal enhancement effect of dielectric NPs on fs-LIBS and provides insights into hydrodynamics of the fs laser-induced plasma generated on CPLA-deposited substrate.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.357
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.236
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it