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Record W2989613303 · doi:10.7939/r3-ccb3-g660

Biodegradation of cycloalkanes under different redox conditions

2019· article· en· W2989613303 on OpenAlexaboutno aff
Luke Gjini

Bibliographic record

VenueUniversity of Alberta Library · 2019
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicBiochemical and biochemical processes
Canadian institutionsnot available
Fundersnot available
KeywordsBiodegradationRedoxChemistryEnvironmental scienceOrganic chemistry

Abstract

fetched live from OpenAlex

Current bitumen extraction technologies used in surface mined oil sands in Alberta, Canada require large volumes of fresh water, which in turn generate large volumes of fluid fine tailings (FFT). Managing these tailings is a major challenge for oil sands operators. Non-aqueous extraction (NAE) is an alternative method which uses hydrocarbon solvents such as cyclohexane, producing smaller volumes of dry tailings with most of the solvent being recoverable post-extraction. However, residual cyclohexane remains in the non-aqueous extraction solids; therefore, developing technology for cycloalkane biodegradation is the aim of this study. Microcosm experiments involve setting up sealed bottles in which a microbial source such as soil or FFT is mixed with nutrient media and/or NAE dry tailings. These microcosms were amended with distinct electron acceptors and cycloalkane NAE solvents to create aerobic, nitrate-reducing, sulfate-reducing, iron-reducing, or methanogenic conditions for cycloalkane biodegradation. These conditions simulated dry tailings management under either upland and wetland reclamation scenarios. Gas chromatography was used to measure cycloalkane concentrations in the microcosm. Electron acceptor depletion and gas production resulting from biodegradation were also being monitored over the course of the experiments. Microcosms containing active microbial communities capable of cycloalkane degradation were found to have three elements in common: maintaining aerobic conditions via oxygen addition, sufficient concentrations of nitrogen and phosphorus, and FFT inoculum. In all other treatments, including anaerobic conditions or other inoculates such as soil or oil sands process affected waters, no significant degradation was observed over the allotted 2 year incubation despite other indications of microbial activity. Therefore, future cycloalkane biodegradation technologies will likely require oxygen and nutrients for adequate cycloalkane removal.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.394

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.172
Teacher spread0.168 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2019
Admission routes1
Has abstractyes

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