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Record W2990213616 · doi:10.1021/cen-09746-scicon1

Making ethylene from air and electrons

2019· article· en· W2990213616 on OpenAlexaboutno aff
Leigh Krietsch Boerner

Bibliographic record

VenueC&EN Global Enterprise · 2019
Typearticle
Languageen
FieldChemistry
TopicVarious Chemistry Research Topics
Canadian institutionsnot available
Fundersnot available
KeywordsElectronEthyleneEngineering physicsMaterials scienceEnvironmental scienceNuclear physicsPhysicsChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

In the hopes of slowing climate change, researchers are seeking ways to get rid of planet-warming carbon dioxide. Making something valuable from it in the process, such as commodity chemicals, is a double win. Researchers at the University of Toronto and the California Institute of Technology now report they have carried off such a trick by improving the efficiency of a process to make the plastics precursor ethylene from CO2 electrochemically (Nature 2019, DOI: 10.1038/s41586-019-1782-2). There’s a huge existing market for ethylene, says Edward Sargent, an electrical engineer at the University of Toronto. But the compound also has a big CO2 footprint because its manufacture is fossil fuel based. “So if we could instead make renewable ethylene,” Sargent says, “we could displace some of the use of fossil fuel–derived ethylene, and we could consume rather than emit CO2 while we’re doing it.” For this work, Sargent and coworkers teamed up

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.591
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.285
Teacher spread0.275 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2019
Admission routes1
Has abstractyes

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