Diffusiophoresis of active colloids in viscoelastic media
Bibliographic record
Abstract
Self-diffusiophoresis of synthetic Janus (Si/Pt) microspheres in the presence of hydrogen peroxide in complex environments is here investigated. We aim to address the single particle dynamics of these active colloids in different viscoelastic fluids. Experimentally, the Janus colloids were dispersed in a dilute polyvinylpyrrolidone (PVP) solution and in a polyacrylamide (PAM) solution in semi-dilute and semi-dilute entangled regime to analyze their Brownian and active motion. These two systems were chosen to probe different relaxation times from relatively short (∼5 ms) for PVP to large (∼14.5 s) for PAM but always smaller than the rotary Brownian motion time scale. Within this regime, we investigate the coupling between the self-propulsion velocity and the medium rheology. Janus particles are found to get physically confined by polymeric entanglements but surprisingly they are able to escape the physical cage in a time scale much shorter than the relaxation time of the polymer solution. This is particularly relevant for application of self-propelling particles in biomedicine, water and soil remediation where complex environments are naturally present.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".