MétaCan
Menu
Back to cohort
Record W2991205046 · doi:10.1039/c9ra07057e

Modelling and prediction of the thermophysical properties of aqueous mixtures of choline geranate and geranic acid (CAGE) using SAFT-γ Mie

2019· article· en· W2991205046 on OpenAlexaff
Silvia Di Lecce, Georgia Lazarou, Siti H. Khalit, Claire S. Adjiman, George Jackson, Amparo Galindo, Lisa McQueen

Bibliographic record

VenueRSC Advances · 2019
Typearticle
Languageen
FieldChemical Engineering
TopicIonic liquids properties and applications
Canadian institutionsKensington Health
FundersRoyal Academy of EngineeringGlaxoSmithKlineEngineering and Physical Sciences Research CouncilEli Lilly and Company
KeywordsAqueous solutionChemistryCholine chlorideEutectic systemCarboxylateGroup contribution methodThermodynamicsIonic liquidAqueous two-phase systemCationic polymerizationPhase (matter)Organic chemistryPhase equilibrium

Abstract

fetched live from OpenAlex

, using data for choline chloride solutions. The osmotic pressure of aqueous mixtures of CAGE at several concentrations is predicted and compared to experimental data obtained as part of our work to assess the accuracy of the modelling platform. The SAFT-γ Mie approach is shown to be predictive, providing a good description of the measured data for a wide range of mixtures and properties. Furthermore, the new group-interaction parameters needed to represent CAGE extend the set of functional groups of the group-contribution approach, and can be used in a transferable way to predict the properties of systems beyond those studied in the current work.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.309
Threshold uncertainty score0.194

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.213
Teacher spread0.197 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations18
Published2019
Admission routes1
Has abstractyes

Explore more

Same venueRSC AdvancesSame topicIonic liquids properties and applicationsFrench-language works237,207