Decorated Tetrathiafulvalene‐Based Ligands: Powerful Chemical Tools for the Design of Single‐Molecule Magnets
Bibliographic record
Abstract
This Minireview covers the design and characterization of coordination lanthanide complexes involving TTF‐based ligands. The specific design of TTF‐based ligands allowed the isolation of complexes with magnetic properties such as Single‐Molecule Magnets (SMMs) behavior and the studies of magnetic modulations due to supramolecular interaction, molecular engineering, magnetic dilution as well as isotopic enrichment. A careful design leads to TTF‐based ligands displaying several coordination sites in order to rationally elaborate polynuclear systems with multi‐SMM behavior or to auto‐assembly SMMs. Their redox activity allowed the investigation of coordination lanthanide complexes in several oxidation states and their consequences on optical and magnetic properties. The complete experimental and theoretical studies of such systems contributed to the understanding of the magnetic properties of lanthanide ions for futures applications in high density storage and quantum computing.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".