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Record W2993607283

Various Influence of Active Сhemical Additives on Hydrogen and Hydrocarbons Combustion

2014· article· en· W2993607283 on OpenAlexvenueno aff
Н. М. Рубцов, Victor I. Chernysh, Georgii I. Tsvetkov, B. S. Seplyarskii

Bibliographic record

VenueInternational Journal of Chemistry · 2014
Typearticle
Languageen
FieldChemical Engineering
TopicAdvanced Combustion Engine Technologies
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryCombustionHydrogenHydrocarbonMethaneIgnition systemInorganic chemistryOrganic chemistryPhotochemistryThermodynamics
DOInot available

Abstract

fetched live from OpenAlex

It is experimentally revealed that the methane combustion inhibitor CCl4 shows no effect on the lower ignition limit of hydrogen combustion. It is established that small amounts (~10-1 %) of chromium hex carbonyl promote combustion of 2H2 + O2 mixture, which manifests itself in increase in the propagation velocity of the flame, thus inhibition of oxidation of isobutene by this additive takes place. Therefore the role of hydrogen atoms in hydrocarbon oxidation is not significant and may result at least in participating in longer reaction chains than in hydrogen oxidation. It means that the kinetic mechanism of inhibiting combustion of hydrocarbons by carbonyls suggested in the literature based on accounting for termination of hydrogen atoms should be refined.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.078
Threshold uncertainty score0.412

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.231
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes1
Has abstractyes

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