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Record W2994230129 · doi:10.1002/cjce.23696

Engineering investigation for the size effect of graphene oxide derived from graphene nanoplatelets in polyurethane composites

2019· article· en· W2994230129 on OpenAlexafffundvenue
Jun Geun Um, Yun‐Seok Jun, Ali Elkamel, Aiping Yu

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2019
Typearticle
Languageen
FieldMaterials Science
TopicCorrosion Behavior and Inhibition
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsGrapheneMaterials scienceComposite materialPolyurethaneOxideUltimate tensile strengthCoatingCorrosionNanotechnologyMetallurgy

Abstract

fetched live from OpenAlex

Abstract In this study, commercial polyurethane (PU) and graphene nanoplatelets (GnP) and their derivative graphene oxide (GO) were used to fabricate PU composites. The size effect of fillers on mechanical properties and anti‐corrosion performance of as‐prepared composites was thoroughly investigated. It was found that GO was more uniformly dispersed in the PU matrix than GnP due to its compatibility with PU. Furthermore, GO led to the higher mechanical properties and anti‐corrosion performance than PU/GnP composites, and the properties were strongly dependant on the size of the GO. Specifically, incorporating large sized GO (GO‐M25) in 0.5 wt% indicated the highest average synergetic tensile modulus up to 53% from the neat PU and the lowest corrosion rate of 0.001 MPY (1 MPY = 0.547 g · m −2 · d −1 ). This phenomenon was attributed to the fact that the larger size of GO is not only uniformly dispersed within the PU matrix but also enables interaction between PU and GO. Conversely, PU composites incorporated with the small sized GO (GO‐C750) did not show elastic behaviour from 0.1 to 0.5 wt% of the filler. This is due to the fact that the high surface area and hydrophilic functionalities of GO‐C750 resulted in hard‐segment content reduction in PU. This research can help in the design of a PU coating that is physically improved and that has a superior anti‐corrosive capacity, particularly for pipelines in the oil‐sands transportation industry.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.325

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.187
Teacher spread0.181 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations23
Published2019
Admission routes3
Has abstractyes

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