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Record W2999108456 · doi:10.1002/aoc.5448

A novel composite derived from a metal organic framework immobilized within electrospun nanofibrous polymers: An efficient methane adsorbent

2020· article· en· W2999108456 on OpenAlex
Ghasem Sargazi, Daryoush Afzali, Ali Mostafavi, Hossein Kazemian

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueApplied Organometallic Chemistry · 2020
Typearticle
Languageen
FieldChemistry
TopicMetal-Organic Frameworks: Synthesis and Applications
Canadian institutionsUniversity of Northern British Columbia
FundersNatural Sciences and Engineering Research Council of CanadaShahid Bahonar University of Kerman
KeywordsAdsorptionPolyvinyl alcoholChemical engineeringComposite numberChemistryNanofiberElectrospinningPorosityPolymerCrystallinityMethaneMetal-organic frameworkResponse surface methodologyThermal stabilityMaterials scienceComposite materialOrganic chemistryChromatography

Abstract

fetched live from OpenAlex

Abstract In this study, tantalum(V) metal organic framework (Ta‐MOF) nanostructure was incorporated within polyvinyl alcohol (PVA) nanofibers to prepare an electrospun porous composite as a novel CH 4 adsorbent. The crystallinity, thermodynamic behavior, and textural properties of the products were investigated using instrumental analyses techniques. The results confirmed that the developed PVA/Ta‐MOF electrospun nanofibrous composite exhibits higher thermal stability, considerable porosity, and larger surface area compared to the parent Ta‐MOF. A 2 k factorial design was used for systematic study of the adsorption process. The results of response surface methodology (RSM) optimization indicated that the highest methane adsorption can be achieved at 24.40 °C and 3.70 bar in 23.60 min. These nano pore sorbents showed a significant potential for CH 4 adsorption due to the presence of Ta‐MOF at the surface of nanofibrous composite compared to many other conventional sorbents that have been already used. This study introduces a novel biocompatible/biodegradable nanofibrous composite material with high methane adsorption performance and potentials for other applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.037
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0020.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0370.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.223
Teacher spread0.210 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it