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Record W2999114776 · doi:10.1039/c9dt04561a

Lithium, sodium, potassium and calcium amine-bis(phenolate) complexes in the ring-opening polymerization of <i>rac</i>-lactide

2020· article· en· W2999114776 on OpenAlexafffund
Katalin Devaine‐Pressing, Fabio J. Oldenburg, Jan P. Menzel, Maximilian A. Springer, Louise N. Dawe, Christopher M. Kozak

Bibliographic record

VenueDalton Transactions · 2020
Typearticle
Languageen
FieldMaterials Science
Topicbiodegradable polymer synthesis and properties
Canadian institutionsRegional Municipality of WaterlooWilfrid Laurier UniversityMemorial University of Newfoundland
FundersNatural Sciences and Engineering Research Council of CanadaMemorial University of NewfoundlandDeutscher Akademischer AustauschdienstCanada Foundation for InnovationDepartment of Natural Resources, Government of Newfoundland and Labrador
KeywordsChemistrySodium hydridePolymerizationMedicinal chemistryTolueneSodiumPolymer chemistryAnionic addition polymerizationSolventLithium (medication)Ligand (biochemistry)Bimetallic stripDimethoxyethaneButyllithiumSalt metathesis reactionInorganic chemistryPolymerOrganic chemistryMetathesisCatalysisPhysical chemistryElectrolyte

Abstract

fetched live from OpenAlex

[L] in toluene. Compounds 1-6 exhibit activity for rac-lactide polymerization under melt and solution conditions. Moderate control of polymer molecular weights was achieved in toluene, whereas polydisperse polymer was obtained under solvent free conditions. MALDI-TOF MS analysis of the polymer end groups revealed a predominantly cyclic nature for the polylactides.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.080
Threshold uncertainty score0.467

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.039
GPT teacher head0.243
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations35
Published2020
Admission routes2
Has abstractyes

Explore more

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