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Defect-Rich, Candied Haws-Shaped AuPtNi Alloy Nanostructures for Highly Efficient Electrocatalysis

2020· article· en· W3005104573 on OpenAlex
Xiaoya Cui, Zhicheng Zhang, Yue Gong, Faisal Saleem, Bo Chen, Yonghua Du, Zhuangchai Lai, Nailiang Yang, Bing Li, Lin Gu, Hua Zhang

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueCCS Chemistry · 2020
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsnot available
FundersBrookhaven National LaboratoryArgonne National LaboratoryMinistry of Education, IndiaNational Natural Science Foundation of ChinaU.S. Department of EnergyNanyang Technological UniversityOffice of ScienceAgency for Science, Technology and ResearchCanadian Light SourceBeijing Synchrotron Radiation FacilityCity University of Hong Kong
KeywordsElectrocatalystAlloyNanostructureMaterials scienceNanotechnologyMetallurgyChemistryElectrochemistryElectrodePhysical chemistry

Abstract

fetched live from OpenAlex

The rational design and synthesis of multimetallic nanostructures (NSs) with rich defects are of significant importance for their diverse applications, including their promising usage as high-efficiency catalysts for alcohol oxidation reaction as a fuel source. Here, we report the synthesis of defect-rich, candied haws-shaped AuPtNi NSs using presynthesized gold (Au) nanowires as templates. The ternary AuPtNi NSs possess rich defects such as twins, stacking faults, and atomic steps. Impressively, the AuPtNi NSs exhibited excellent mass and specific activities toward methanol and ethanol oxidation reactions under acidic conditions. Our current work paves the way for the rational design and controlled synthesis of defect-rich multimetallic NSs to boost their performances in catalytic reactions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.052
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.207
Teacher spread0.199 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it