Diagenetic Pore Fluid Evolution and Dolomitization of the Silurian and Devonian Carbonates, Huron Domain of Southwestern Ontario: Petrographic, Geochemical and Fluid Inclusion Evidence
Bibliographic record
Abstract
Core samples from two deep boreholes were analyzed for petrographic, stable and Sr isotopes, fluid inclusion microthermometry and major, minor, trace and rare-earth elements (REE) of different types of dolomite in the Silurian and Devonian carbonates of the eastern side of the Michigan Basin provided useful insights into the nature of dolomitization, and the evolution of diagenetic pore fluids in this part of the basin. Petrographic features show that both age groups are characterized by the presence of a pervasive replacive fine-crystalline (<50 µm) dolomite matrix (RD1) and pervasive and selective replacive medium crystalline (>50–100 µm) dolomite matrix (RD2 and RD3, respectively). In addition to these types, a coarse crystalline (>500 µm) saddle dolomite cement (SD) filling fractures and vugs is observed only in the Silurian rocks. Results from geochemical and fluid inclusion analyses indicate that the diagenesis of Silurian and Devonian formations show variations in terms of the evolution of the diagenetic fluid composition. These fluid systems are: (1) a diagenetic fluid system that affected Silurian carbonates and was altered by salt dissolution post-Silurian time. These carbonates show a negative shift in δ18O values (dolomite δ18O average: −6.72‰ VPDB), Sr isotopic composition slightly more radiogenic than coeval seawater (0.7078–0.7087), high temperatures (RD2 and SD dolomite Th average: 110 °C) and hypersaline signature (RD2 and SD dolomite average salinity: 26.8 wt.% NaCl eq.); and (2) a diagenetic fluid system that affected Devonian carbonates, possibly occurred during the Alleghenian orogeny in Carboniferous time and characterized by a less pronounced negative shift in δ18O values (dolomite δ18O average: −5.74‰ VPDB), Sr isotopic composition in range with the postulated values for coeval seawater (0.7078–0.7080), lower temperatures (RD2 dolomite Th average: 83 °C) and less saline signature (RD2 dolomite average salinity: 20.8 wt.% NaCl eq.).
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".