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Record W3007258346 · doi:10.1039/c9tc06261k

Controlling the nuclearity and topology of cobalt complexes through hydration at the ppm level

2020· article· en· W3007258346 on OpenAlexafffund
Raúl Castañeda, Mathieu Rouzières, Jaclyn L. Brusso

Bibliographic record

VenueJournal of Materials Chemistry C · 2020
Typearticle
Languageen
FieldMaterials Science
TopicMagnetism in coordination complexes
Canadian institutionsWilfrid Laurier UniversityUniversity of Ottawa
FundersOntario Ministry of Research, Innovation and ScienceConsejo Nacional de Ciencia y TecnologíaCentre National de la Recherche ScientifiqueEuropean Cooperation in Science and TechnologyUniversity of Ottawa
KeywordsCobaltTopology (electrical circuits)Materials scienceCrystallographyIonInorganic chemistryChemistryMetallurgyCombinatoricsMathematicsOrganic chemistry

Abstract

fetched live from OpenAlex

Polynuclear cobalt complexes in which nuclearity and topology can be controlled <italic>via</italic> ppm level control over the degree of hydration (300 <italic>vs.</italic> 10 000 ppm). Structural and magnetic analysis were used to elucidate the spin state of the cobalt ions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.014
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.050
GPT teacher head0.273
Teacher spread0.223 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2020
Admission routes2
Has abstractyes

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Same venueJournal of Materials Chemistry CSame topicMagnetism in coordination complexesFrench-language works237,207