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Record W3010015534 · doi:10.3390/atmos11030238

First Evidences of Methyl Chloride (CH3Cl) Transport from the Northern Italy Boundary Layer during Summer 2017

2020· article· en· W3010015534 on OpenAlexaboutno aff
Paolo Cristofanelli, Jgor Arduini, F. Calzolari, U. Giostra, Paolo Bonasoni, Michela Maione

Bibliographic record

VenueAtmosphere · 2020
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsnot available
FundersH2020 Research InfrastructuresMinistero dell’Istruzione, dell’Università e della Ricerca
KeywordsEnvironmental scienceOutflowAtmosphere (unit)Ozone layerAtmospheric sciencesEmission inventoryOzone depletionClimatologyMeteorologyGeologyGeographyStratosphereAir quality index

Abstract

fetched live from OpenAlex

Methyl Chloride (CH3Cl) is a chlorine-containing trace gas in the atmosphere contributing significantly to stratospheric ozone depletion. While the atmospheric CH3Cl emissions are predominantly caused by natural sources on the global budget, significant uncertainties still remain for the anthropogenic CH3Cl emission strengths. In summer 2007 an intensive field campaign within the ACTRIS-2 Project was hosted at the Mt. Cimone World Meteorological Organization/Global Atmosphere Watch global station (CMN, 44.17° N, 10.68° E, 2165 m a.s.l.). High-frequency and high precision in situ measurements of atmospheric CH3Cl revealed significant high-frequency variability superimposed on the seasonally varying regional background levels. The high-frequency CH3Cl variability was characterized by an evident cycle over 24 h with maxima during the afternoon which points towards a systematic role of thermal vertical transport of air-masses from the regional boundary layer. The temporal correlation analysis with specific tracers of anthropogenic activity (traffic, industry, petrochemical industry) together with bivariate analysis as a function of local wind regime suggested that, even if the role of natural marine emissions appears as predominant, the northern Italy boundary layer could potentially represent a non-negligible source of CH3Cl during summer. Since industrial production and use of CH3Cl have not been regulated under the Montreal Protocol (MP) or its successor amendments, continuous monitoring of CH3Cl outflow from the Po Basin is important to properly assess its anthropogenic emissions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.031
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0060.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.029
GPT teacher head0.218
Teacher spread0.189 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2020
Admission routes1
Has abstractyes

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