Triethylene Glycol Substituted Diketopyrrolopyrrole‐ and Isoindigo‐Dye Based Donor–Acceptor Copolymers for Organic Light‐Emitting Electrochemical Cells and Transistors
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Abstract Triethylene glycol, a common side chain, is attached to two different dye moieties, diketopyrrolopyrrole (DPP) and isoindigo (II), and their bromo derivative monomers are copolymerized, respectively, with common bisstannyl alkylated bithiophene via Stille coupling. The resulting donor–acceptor low‐bandgap copolymers, namely, PTDPP‐DT and PTII‐DT, are rationally deigned and synthesized conjugated polymeric systems suitable for doping. Both polymers are successfully investigated as single‐component and composite‐system‐based electrochemical transistors and light‐emitting electrochemical cells. A PTDPP‐DT thin film exhibits relatively high electrical conductivity of up to 80 S cm −1 in the electrochemically doped state, whereas PTII‐DT thin film prevents the macroscopic charge transport due to a large‐scale crystalline disorientation. Upon evaluating both polymers as active conjugated materials in light‐emitting electrochemical cells, they both exhibit emission under efficient electron/hole doping conditions.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it