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Record W3015139653 · doi:10.1149/1945-7111/ab856b

Review—Conducting Polymer-Based Binders for Lithium-Ion Batteries and Beyond

2020· article· en· W3015139653 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueJournal of The Electrochemical Society · 2020
Typearticle
Languageen
FieldEngineering
TopicAdvanced Battery Materials and Technologies
Canadian institutionsUniversity of Manitoba
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of Manitoba
KeywordsBattery (electricity)Lithium (medication)Materials scienceLimitingBottleneckNanotechnologyEnergy densityLithium-ion batteryComposite numberComputer scienceEngineering physicsComposite materialMechanical engineeringEngineeringEmbedded system

Abstract

fetched live from OpenAlex

In the search for active Lithium-ion battery materials with ever-increasing energy density, the limits of conventional auxiliary materials, such as binders and conducting additives are being tested. Binders adhere to active substances and current collectors, yielding an interconnected electrode structure that ensures mechanical integrity during the (de-)lithiation process. Even though the battery binder only accounts for a fraction of battery weight and cost, it is a bottleneck technology in the deployment of high energy density active materials that experience significant volume variation and side-reactions. This review paper discusses research on alternative binders derived from conducting polymers (CPs). The use of CPs in binders enables mechanically flexible electronic contacts with the active material with the goal of accommodating larger volume changes within the electrode. Following a summary of the reasoning behind the use of CP-based binders, their rational design is reviewed, including novel composite syntheses and chemical modifications. A new class of multifunctional CP-based binders exhibits promising properties such as high electronic conductivity, the ability for aqueous processing, and efficient binding that tackle the limiting features of traditional binders. The practical application of these binders in Li-ion batteries and beyond is summarized, yielding an outline of current achievements, and a discussion of remaining knowledge gaps and possible future development of such binders.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.209
Threshold uncertainty score0.267

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.235
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it