Solvent effects leading to a variety of different 2D structures in the self-assembly of a crystalline-coil block copolymer with an amphiphilic corona-forming block
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Bibliographic record
Abstract
) (the subscripts refer to the mean degrees of polymerization), in which the corona-forming block is a random brush copolymer of hydrophobic tetradecyl methacrylate (TDMA) and hydrophilic oligo(ethylene glycol) methyl ether methacrylate (OEGMA). Thus, the corona is amphiphilic. This BCP generates a remarkable series of different structures when subjected to crystallization-driven self-assembly (CDSA) in solvents of different polarity. Long ribbon-like micelles formed in isopropanol, and their lengths could be controlled using both self-seeding and seeded growth protocols. In hexanol, the BCP formed more complex structures. These objects consisted of oval platelets connected to long fiber-like micelles that were uniform in width but polydisperse in length. In octane, relatively uniform rectangular platelets formed. Finally, a distinct morphology formed in a mixture of octane/hexanol, namely uniform oval structures, whose height corresponded to the fully extended PFS block. Both long and short axes of these ovals increased with the initial annealing temperature and with the BCP concentration. The self-seeding protocol also afforded uniform two-dimensional structures. Seeded growth experiments, in which a solution of the BCP in THF was added to a colloidal solution of the oval micelles led to a linear increase in area while maintaining the aspect ratio of the ovals. These experiments demonstrate the powerful effect of the amphiphilic corona chains on the CDSA of a core crystalline BCP in solvents of different hydrophilicity.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it