MétaCan
Menu
Back to cohort

Effect of TiO2 Nanoparticles on Barrier and Mechanical Properties of PVA Films

2021· article· en· W3023575261 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of membrane science and research · 2021
Typearticle
Languageen
FieldMaterials Science
TopicPolymer Nanocomposite Synthesis and Irradiation
Canadian institutionsUniversity of Ottawa
Fundersnot available
KeywordsNanocompositeMaterials sciencePolyvinyl alcoholNanoparticleScanning electron microscopeChemical engineeringTitanium dioxideOxygen permeabilityComposite materialPolymerUltimate tensile strengthDynamic mechanical analysisTransmission electron microscopyVinyl alcoholNanotechnologyChemistryOxygenOrganic chemistry

Abstract

fetched live from OpenAlex

Nanocomposites made of nanoparticles embedded in the matrix of polymer membranes have been used in the food packaging industry due to their enhanced barrier and mechanical properties. In this study, nanocomposite films made of polyvinyl alcohol (PVA) and titanium dioxide nanoparticles (size = 20 nm, 1 and 2 wt%) were prepared by the solvent casting method and their mechanical, physical, and barrier properties were determined. Scanning electron microscopy (SEM) and X-ray diffraction analysis (XRD) were performed for characterizing the morphology of PVA/TiO2 nanocomposite films. Water vapor permeability (WVP) and oxygen transmission rate (OTR) were measured for mixed matrix PVA films for two concentrations of TiO2 nanoparticles. The results revealed that OTR and WVP decreased with increasing TiO2 nanoparticle concentration. Elongation at the break point and Young’s modulus both increased whereas strength decreased. XRD measurements confirmed the completely dispersed structure formed in the TiO2 nanocomposites. SEM micrographs showed an identical distribution at 1 and 2 wt% levels of TiO2 nanoparticles.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.008
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.280

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0080.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.033
GPT teacher head0.325
Teacher spread0.292 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it