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Record W3024277595 · doi:10.1149/ma2020-01211261mtgabs

Electrochemical Pressure Impedance Spectroscopy As a Diagnostic Method for Hydrogen-Air Polymer Electrolyte Fuel Cells

2020· article· en· W3024277595 on OpenAlexaff
Qingxin Zhang, Michael Eikerling, Byron D. Gates

Bibliographic record

VenueECS Meeting Abstracts · 2020
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsSimon Fraser University
Fundersnot available
KeywordsDielectric spectroscopyElectrolyteHydrogen fuelWater transportCathodeHydrogenMaterials scienceProton exchange membrane fuel cellElectrochemistryEnvironmental scienceAmbient pressureWork (physics)Chemical engineeringFuel cellsChemistryElectrical engineeringElectrodeMechanical engineeringEnvironmental engineeringEngineeringMeteorologyPhysics

Abstract

fetched live from OpenAlex

Water transport in an operating hydrogen-air fuel cells has gathered the interests of both researchers and developers working on fuel cells. Better water removal can extend the operation regime of fuel cells and, therefore, increase its maximum cell power and overall energy efficiency. However, state-of-art in situ fuel cell diagnostics cannot provide an insight into the water transport phenomenon. Recent research shows that pressure controlling techniques have the potential to address issues with water transport. The purpose of this work is to develop an in-situ diagnostic tool from cathode pressure oscillations for hydrogen-air polymer electrolyte fuel cells named as electrochemical pressure impedance spectroscopy (EPIS). The response between the cell voltage and the pressure oscillations is analogous to the electrochemical impedance spectroscopy (EIS)(See image). The relation between EPIS response and water transport phenomenon is intensively studied in this work. With the help from our industrial partner, Greenlight Innovation Corp., we are able to integrate this diagnostic method into a fuel cell test station. Experimental data are fitted by the mathematical derivation of the response from theoretical cell components from which are extracted crucial parameters and diagnostic information for water transport. Figure 1

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.001
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.227
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2020
Admission routes1
Has abstractyes

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