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Record W3024480793 · doi:10.1098/rspa.2019.0769

The impacts of ocean acidification on marine trace gases and the implications for atmospheric chemistry and climate

2020· review· en· W3024480793 on OpenAlexafffund
Frances E. Hopkins, Parvadha Suntharalingam, Marion Gehlen, Oliver Andrews, Stephen D. Archer, Laurent Bopp, Erik T. Buitenhuis, Isabelle Dadou, Robert A. Duce, Nadine Goris, Tim Jickells, Martin Johnson, Fiona Seh-Lin Keng, Cliff S. Law, Kitack Lee, Peter S. Liss, Martine Lizotte, J. Colin Murrell, Hema Naik, Andrew P. Rees, Jörg Schwinger, Phillip Williamson

Bibliographic record

VenueProceedings of the Royal Society A Mathematical Physical and Engineering Sciences · 2020
Typereview
Languageen
FieldEarth and Planetary Sciences
TopicOcean Acidification Effects and Responses
Canadian institutionsUniversité Laval
FundersH2020 EnvironmentNatural Sciences and Engineering Research Council of CanadaUniversity of East AngliaUniversiti MalayaNatural Environment Research CouncilNational Research Foundation of KoreaNorges ForskningsrådSight Research UK
KeywordsTrace gasOcean acidificationBiogeochemistryAtmospheric chemistryEnvironmental scienceDimethyl sulfideUpwellingOceanographyClimate changeOcean chemistryEnvironmental chemistryEarth scienceChemistryAtmospheric sciencesGeologySeawater

Abstract

fetched live from OpenAlex

Surface ocean biogeochemistry and photochemistry regulate ocean–atmosphere fluxes of trace gases critical for Earth's atmospheric chemistry and climate. The oceanic processes governing these fluxes are often sensitive to the changes in ocean pH (or p CO 2 ) accompanying ocean acidification (OA), with potential for future climate feedbacks. Here, we review current understanding (from observational, experimental and model studies) on the impact of OA on marine sources of key climate-active trace gases, including dimethyl sulfide (DMS), nitrous oxide (N 2 O), ammonia and halocarbons. We focus on DMS, for which available information is considerably greater than for other trace gases. We highlight OA-sensitive regions such as polar oceans and upwelling systems, and discuss the combined effect of multiple climate stressors (ocean warming and deoxygenation) on trace gas fluxes. To unravel the biological mechanisms responsible for trace gas production, and to detect adaptation, we propose combining process rate measurements of trace gases with longer term experiments using both model organisms in the laboratory and natural planktonic communities in the field. Future ocean observations of trace gases should be routinely accompanied by measurements of two components of the carbonate system to improve our understanding of how in situ carbonate chemistry influences trace gas production. Together, this will lead to improvements in current process model capabilities and more reliable predictions of future global marine trace gas fluxes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: none
Teacher disagreement score0.009
Threshold uncertainty score0.017

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0010.001
Open science0.0000.001
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.240
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreReview

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations75
Published2020
Admission routes2
Has abstractyes

Explore more

Same venueProceedings of the Royal Society A Mathematical Physical and Engineering SciencesSame topicOcean Acidification Effects and ResponsesFrench-language works237,207