Experimental Evidence That Permafrost Thaw History and Mineral Composition Shape Abiotic Carbon Cycling in Thermokarst-Affected Stream Networks
Bibliographic record
Abstract
Mounting evidence suggests that biogeochemical processing of permafrost substrate will amplify dissolved inorganic carbon (DIC=E[CO2,HCO3–,CO32–]) production within Arctic freshwaters. The effects of permafrost thaw on DIC may be particularly strong where terrain subsidence following thaw (thermokarst) releases large amounts of sediment into fluvial networks. The mineral composition and chemical weathering of these sediments has critical yet untested implications for the degree to which streams represent a source of CO2 to the atmosphere versus a source of bicarbonate to downstream environments. Here, we experimentally determine the effects of mineral weathering on fluvial CO2 by incubating sediments collected from three retrogressive thaw slump features on the Peel Plateau (NWT, Canada). Prehistoric warming and contemporary thermokarst have exposed sediments on the Peel Plateau to varying degrees of thaw and chemical weathering, allowing us to test the role of permafrost and substrate mineral composition on CO2:HCO3– balance. We found that recently-thawed sediments (within years to decades) and previously un-thawed diamicton from deeper permafrost generated significant solutes and DIC. These solutes and the mineralogy of sediments suggested that carbonate weathering coupled with sulfide oxidation was a net source of abiotic CO2. Yet, on average, 30% of this CO2 was converted to bicarbonate via carbonate buffering reactions. In contrast, the mineralogy and geochemical trends associated with sediments from the modern and paleo-active layer, which were exposed to thaw over longer timescales, more strongly reflected silicate weathering. In treatments with sediment from the modern and paleo-active layer, minor carbonate and sulfide weathering resulted in some DIC and net CO2 production. This CO2 was not measurably diminished by carbonate buffering. Together, these trends suggest that prior exposure to thaw and weathering on the Peel Plateau reduced carbonate and sulfide in upper soil layers. We conclude that thermokarst unearthing deeper tills on the Peel Plateau will amplify regional inorganic carbon cycling for decades to centuries. However, previously-undocumented CO2 consumption via carbonate buffering may partly counterbalance CO2 production and release to the atmosphere. Regional variability in the mineral composition of permafrost, thaw history, and thermokarst intensity are among the primary controls on mineral weathering within permafrost carbon-climate feedbacks.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".