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Record W3029924580 · doi:10.18331/brj2020.7.2.4

Qualitative role of heterogeneous catalysts in biodiesel production from Jatropha curcas oil

2020· article· en· W3029924580 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueBiofuel Research Journal · 2020
Typearticle
Languageen
FieldEngineering
TopicBiodiesel Production and Applications
Canadian institutionsnot available
Fundersnot available
KeywordsJatropha curcasCatalysisRaw materialTransesterificationBiodieselMaterials scienceBiodiesel productionYield (engineering)JatrophaChemical engineeringNickelMetalOrganic chemistryChemistryMetallurgyBiotechnology

Abstract

fetched live from OpenAlex

Biodiesel properties are in general attributed to the composition and properties of the oil feedstock used, overlooking the possible impacts of the catalyst preparation details. In light of that, the impacts of different catalyst preparation techniques alongside those of different support materials on the yield, composition, and fuel properties of biodiesels produced from the same oil feedstock were investigated. More specifically, tri-metallic (Fe-Co-Ni) catalyst was synthesized through two different techniques (green synthesis and wet impregnation) using MgO or ZnO as support material. The generated catalyst pairs, i.e., Fe-Co-Ni/MgO and Fe-Co-Ni/ZnO prepared by wet impregnation and Fe-Co-Ni-MgO and Fe-Co-Ni-ZnO prepared by green synthesis (using leaf extracts) were used in the transesterification process of Jatropha curcas oil. Detailed morphological properties, composition, thermal stability, crystalline nature, and functional groups characterization of the catalysts were also carried out. Using Box-Behnken Design response surface methodology, it was found that the green-synthesized Fe-Co-Ni-MgO catalyst resulted in the highest biodiesel yield of 97.9%. More importantly, the fatty acid methyl ester (FAME) profiles of the biodiesels produced using the four catalysts as well as their respective fuel properties were different in spite of using the same oil feedstock.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.086
Threshold uncertainty score0.436

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.116
GPT teacher head0.380
Teacher spread0.264 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it