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Record W3033574916 · doi:10.1002/ange.202007036

Innenrücktitelbild: Crystal Engineering of Room Temperature Phosphorescence in Organic Solids (Angew. Chem. 25/2020)

2020· article· de· W3033574916 on OpenAlex
Ehsan Hamzehpoor, Dmitrii F. Perepichka

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAngewandte Chemie · 2020
Typearticle
Languagede
FieldChemistry
TopicChemical Reactions and Mechanisms
Canadian institutionsMcGill University
Fundersnot available
KeywordsPhosphorescenceChemistryCrystal engineeringCrystal (programming language)Crystal structureCrystallographyPhysicsFluorescenceOptics

Abstract

fetched live from OpenAlex

Die Molekülpackung bestimmt das photophysikalische Verhalten organischer Luminogene. In ihrer Zuschrift auf S. 10063 berichten E. Hamzehpoor und D. F. Perepichka über eine Serie von Azatriangulentrionen (TANGO), deren Lumineszenzeigenschaften von der Größe der Substituenten abhängen. Die gleiche Ausrichtung der Carbonylgruppen in sterisch unbefrachteten TANGO-Derivaten führt zu Raumtemperatur-Phosphoreszenz (Triplett-Emission) mit bis zu 42 % Quantenausbeute, während eine 60°-Drehung aufgrund sperriger tert-Butylgruppen in einer nahezu reinen Fluoreszenz resultiert.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.032
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.208
Teacher spread0.200 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it