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Record W3041544777 · doi:10.1149/09707.0869ecst

Hydrodynamic Studies of Ethanol Oxidation at Pt and PtRu Catalysts at Elevated Temperatures

2020· article· en· W3041544777 on OpenAlexaff
Azam Sayadi, Peter G. Pickup

Bibliographic record

VenueECS Transactions · 2020
Typearticle
Languageen
FieldChemistry
TopicElectrochemical Analysis and Applications
Canadian institutionsMemorial University of Newfoundland
Fundersnot available
KeywordsStoichiometryCatalysisElectrochemistryEthanolCyclic voltammetryChemistryVoltammetryOxidation stateInorganic chemistryElectrodeAnalytical Chemistry (journal)Physical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Rotating disk voltammetry (RDV) has been applied to study the electrochemical oxidation of ethanol at Pt/C and PtRu/C electrodes at three different temperatures. Steady-state currents produced linear Koutecky–Levich (K-L) plots, in most cases, which provide estimates of the number of electrons transferred (stoichiometry). The PtRu/C catalyst showed better performances than Pt/C in terms of both activity and the number of electrons transferred at higher temperatures. Results showed that RDV can provide valuable stochiometric information for assessment of the completeness of ethanol oxidation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.429

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.253
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2020
Admission routes1
Has abstractyes

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