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Record W3041618478 · doi:10.1021/acssuschemeng.0c03903

Synthesis and Characterization of Bio-pitch from Bio-oil

2020· article· en· W3041618478 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2020
Typearticle
Languageen
FieldEngineering
TopicFiber-reinforced polymer composites
Canadian institutionsNatural Resources CanadaUniversité Laval
FundersNatural Sciences and Engineering Research Council of CanadaFonds de recherche du Québec – Nature et technologiesUniversité LavalAlcoa
KeywordsCoal tarCharacterization (materials science)Softening pointCarbon fibersPyrolysisEnvironmentally friendlyAnodeMaterials scienceChemical engineeringElemental analysisFraction (chemistry)Chemistrytar (computing)CoalOrganic chemistryNanotechnologyComposite materialComputer science

Abstract

fetched live from OpenAlex

Coal-tar-pitch (CTP) is a fossil carbon material, currently used as a the binder in carbon anode manufacturing process. Regardless of the technical benefits of coal-tar-pitch, it contains polycyclic aromatic hydrocarbons (PAHs), known to be carcinogenic for humans and detrimental to the environment. To overcome this challenge, research was carried out to search for a suitable substitution with health- and environmental-friendly properties. Bio-pitch, produced from bio-oil, could be a potential alternative binder for the carbon anode manufacturing process, due to its similarity with CTP. However, the properties of bio-pitch could be significantly different from those of CTP depending on its origins and process conditions. This study focuses on the synthesis of bio-pitches from bio-oil under different vacuum extraction conditions and characterization of its physical and chemical properties, aiming at the determination of the conditions that may result in suitable properties for anode formulation. Both typical characterization and profound chemical analysis of bio-pitches were carried out, including the determination of density, softening point, coking value, quinoline insolubles, PAH content, molecular weight, viscosity, and elemental composition and the identification of chemical structures. In addition, the condensed fraction produced was also analyzed to identify the reaction mechanisms occurring during the pyrolysis process.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.035
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.153
Teacher spread0.149 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it