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Record W3067963978 · doi:10.1002/cey2.73

Biomass‐derived nonprecious metal catalysts for oxygen reduction reaction: The demand‐oriented engineering of active sites and structures

2020· article· en· W3067963978 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueCarbon Energy · 2020
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsInstitut National de la Recherche Scientifique
FundersFonds de recherche du Québec – Nature et technologiesNatural Sciences and Engineering Research Council of CanadaNational Natural Science Foundation of ChinaCentre québécois sur les matériaux fonctionnelsInstitut national de la recherche scientifique
KeywordsCatalysisBiomass (ecology)Renewable energyPrecious metalFuel cellsElectrochemical energy conversionRational designElectrochemistryMetalOxygen reduction reactionPlatinumChemistryNanotechnologyChemical engineeringMaterials scienceProcess engineeringBiochemical engineeringEnvironmental scienceOrganic chemistryEngineeringElectrode

Abstract

fetched live from OpenAlex

Abstract Oxygen reduction reaction (ORR) is an important electrochemical process for renewable energy conversion and storage applications such as fuel cells and metal‐air batteries. ORR is sluggish in kinetics and requires a large amount of platinum group metal (PGM)‐based catalysts to facilitate its slow reaction rate. Application of precious metals raises the cost and decreases the competitivity of these devices in the market. To address this challenge, PGM‐free ORR catalysts have been intensively investigated as an alternative to replace the PGM‐based catalysts and to promote the deployment of ORR‐related applications. In particular, the biomass holds promising potential to be used as the precursor material for PGM‐free ORR catalysts. This pathway has gained more and more attention in recent years. In this review, recent advances regarding biomass‐derived ORR catalysts are summarized with a focus on the rational design of both active sites and porous structures which are the two key factors in determining ORR performance of catalysts. At the end, the perspectives of development of biomass‐derived catalysts is discussed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.764

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.201
Teacher spread0.192 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it