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Record W3080736653 · doi:10.1002/cjce.23868

Working diagrams to identify the operating range of a bubbling fluidized bed reactor for the <scp>CO<sub>2</sub></scp> methanation

2020· article· en· W3080736653 on OpenAlexafffundvenue
Jennifer Martin‐del‐Campo, Jan Kopyscinski

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2020
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysts for Methane Reforming
Canadian institutionsMcGill University
FundersNatural Sciences and Engineering Research Council of CanadaConsejo Nacional de Ciencia y Tecnología
KeywordsMethanationFluidized bedNuclear engineeringFluidizationMaterials scienceWaste managementEnvironmental scienceHydrogenChemistryProcess engineeringEngineering

Abstract

fetched live from OpenAlex

Abstract Fluidized bed reactors for the catalytic CO 2 methanation is a promising concept within the power‐to‐gas (methane) process. Due to the intermittency of renewable electricity generation and thus hydrogen production, the subsequent methanation reactor should also be able to operate at lower feed flow rates, while maintaining fluidized bed conditions. Bubbling fluidized bed reactors offer the required flexibility as shown with the new type of working diagrams. These working diagrams visualize a decision window for (a) determining the reactor diameter and (b) operating the fluidized bed reactor with a turndown ratio of 0.5‐1.1. Reducing the turndown ratio (ie, inlet flow rate) could lead to defluidization, thus increasing temperature or reducing the pressure are alternatives to maintain fluidization conditions. The former method is not desired, as a temperature increase would significantly reduce the CH 4 yield due to thermodynamic constraints and therefore reduce the overall efficiency. An industrial CO 2 methanation reactor, for example, that is designed for 10 bara (1 bara = 100 kPa) and 340°C with a total inlet flow rate of 5000 m 3 N · h −1 (H 2 /CO 2 = 4) can be operated at a turndown ratio of 0.5 (2500 m 3 N · h −1 ) at the same temperature and the same u 0 /u mf ratio by reducing the pressure to 5 bara with only a slight decrease in the CO 2 equilibrium conversion from 96.7% to 94.6%.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.008
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.023
Threshold uncertainty score0.923

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.008
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.027
GPT teacher head0.251
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2020
Admission routes3
Has abstractyes

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